By Irina A. Maretina,Boris I. Ionin
Acetylene structures current a brand new path to cyclic compounds as a substitute to more conventional equipment hired in classical natural chemistry. The synthesis of cyclic constructions in keeping with acetylene platforms has very important functions within the formation of nanostructures, clearly happening compounds and chemosensory fabrics for the layout of nonlinear optics, digital and photonic devices.
Alkynes in Cycloadditions offers a contemporary evaluation of regioselective synthesis of fragrant and non-aromatic carbocyclic and heterocyclic ring platforms established totally on [2+2+2] and [4+2] cycloadditions, and different reactions of acetylenic devices together with enediynes and enyne-allenes.
Topics coated include:
- New suggestions for the formation of fragrant and polynuclear hydrocarbons in accordance with (Z)-hex-3-en-1,5-diyne and (Z)-hepta-1,2,4-triene-6-yne blocks.
- One-step synthesis of benzene derivatives, β-substituted naphthalenes and acenes through the cycloaromatization of enediynes and enyne-allenes by way of Bergman, Myers-Saito and Shmittel.
- Mechanisms of cycloaromatization leading to the formation of fulvene and indene systems.
- Heterocyclization concerning enyne-carbodiimides.
- New achievements in classical cycloaddition reactions corresponding to the Diels-Alder condensation with acetylenic dienophiles and [2+2] cycloadditions with acetylene components
Alkynes in Cycloadditions provides a entire precis of the literature on tools for the synthesis of ring platforms from acetylenes for tutorial researchers operating within the fields of natural synthesis, actual natural chemistry, organometallic chemistry, catalysis, fabrics technology, nanomaterials and biochemistry.
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Extra info for Alkynes in Cycloadditions
Alkynes in Cycloadditions by Irina A. Maretina,Boris I. Ionin